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Victor Louis Alfred was the younger son of Joseph Hyacinthe François de Paule de Rigaud, Comte de Vaudreuil (1740–1817), who was a French connoisseur and art collector at the court of King Louis XVI. He was the alleged lover of Gabrielle de Polastron, Duchesse de Polignac (1749–1793), a favourite of Marie Antoinette. The Duchess died in Vienna in 1793 and Joseph married his twenty-year-old cousin, Marie Josephine Hyacinthe Victoire de Vaudreuil (1774-1851) in England two years later. Together they had two sons, Charles Philippe Louis Joseph Alfred (1796-1880) and Victor Louis Alfred (1798-1834).
Joseph championed the work of Élisabeth-Louise Vigée-Le Brun who painted two known portraits of him in 1784.